There is no exact way to guess on the amount that you can take off a head to dial in an exact compression, start off small and check with a "good" compression tester.
I continuesly get calls on this. If you want to guess then mill away, but if you want to be correct in modding your motor. Mill, check and document the increase. This way you will reach the compression to match the octane that you are running and you do not detonate the thing apart.