Ha! One of us must have been drinking the high octane if you are seeing triple.
Crazy Dave, the higher octane works by being a bit more slower burning and resistant to ignition (resistant to sudden flame front propagation due to spontaneous ignition in several locations). So to answer your earlier question:
"So when exactly does the higher octane play it's roll..? Before or after ignition...? Or both.."
The answer is both.
Pre-ignition is caused by:
1) the fuel/air being too ready to ignite due to the heat, pressure, and/or ignition source, and
2) once ignited the fuel/air burns too fast due to
- a) the burn rate of the fuel under rapidly rising heat and pressure
- b) multiple spontaneous ignitions due to the rapidly rising heat and pressure
- c) the volume not increasing fast enough due to where in the stroke the ignition started
- d) mixture droplet size, velocity and homogeneity supporting rapid burn.
A perfect stoichiometric mixture of completely vaporized fuel tends to burn explosively (overly fast burn rate), especially when heated to near or past ignition temperature and subject to high pressures. Our tools to resist this explosively fast burning is:
1) higher octane fuel (slower burning and harder to ignite under pressure)
2) less cylinder pressure (lower compression and/or cylinder filling)
3) increase to volume faster or with less resistance (later timing, better crank angles)
4) increase fuel droplet size (carb, intake or inlector selection or alteration)
5) cooler temperatures (thermostat, head material, quench area)
6) mixture ratio (jetting slightly rich)
7) mixture swirl velocity (port layout and squish design)
As you can see, octane is only one tool in your toolbox to battle detonation.
Almost all of these tools pit fuel (and power) efficiency against detonation resistance.
It is a delicate balance.